Hi,
How can I use visual studio c/c++ 2010 express with KDevelop ?

It should work that you just install it and then start KDevelop via the "KDevelop -- MSVC compiler" shortcut in the start menu. That is supposed to set up the environment for the compiler, and then you can just build your cmake project or whatever with MSVC from within kdevelop. I guess nobody tested it with VS 2010 specifically so far, though, so let us know if it works